Silicon tetrachloride

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil330.KN/APCR Inc., 1990BS
Tboil330.28KN/ARugina, Gaspar, et al., 1987Uncertainty assigned by TRC = 0.5 K; TRC
Tboil330.75KN/ASauer and Hadsell, 1948Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Tfus204.4KN/AAnonymous, 1955Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Tc0.KN/AParker and Robinson, 1927TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
29.9305.N/AJain and Yadav, 1973Based on data from 298. to 313. K.; AC
30.4288.N/ACapková and Fried, 1964Based on data from 273. to 326. K.; AC
30.2290.IJenkins and Chambers, 1954Based on data from 275. to 330. K.; AC
30.1303.N/AKearby, 1936Based on data from 273. to 333. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
298. to 313.4.828921616.5465.305Jain and Yadav, 1973, 2Coefficents calculated by NIST from author's data.
273.70 to 325.684.003291149.847-43.044Capková and Fried, 1964Coefficents calculated by NIST from author's data.
275.4 to 330.14.097771200.-37.Jenkins and Chambers, 1954 

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
43.3 ± 0.1175. to 204.MGBalk and Dong, 1964AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
7.72204.7Devyatykh, Guesev, et al., 1985AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Rugina, Gaspar, et al., 1987
Rugina, T.; Gaspar, M.; Sacarescu, L., Liquid-vapor equilibrium for a binary system of dichlorodimethyl-silane with trichloromethylsilane, chloromethylsilane and silicontetrachloride., Rev. Chim. (Bucharest), 1987, 38, 680. [all data]

Sauer and Hadsell, 1948
Sauer, R.O.; Hadsell, E.M., Azeotropes of Trimethylchlorosilane and Silicon Tetrachloride, J. Am. Chem. Soc., 1948, 70, 4258-9. [all data]

Anonymous, 1955
Anonymous, R., , Am. Pet. Inst. Res. Proj. 45, Tech. Rep. 14, No. 1, Ohio State Univ., 1955. [all data]

Parker and Robinson, 1927
Parker, T.W.; Robinson, P.L., Critical Temperatures of Boron Trichloride and Silicon Tetrachloride., J. Chem. Soc., 1927, 1927, 2977-81. [all data]

Jain and Yadav, 1973
Jain, D.V.S.; Yadav, O.P., Indian J. Chem., 1973, 11, 28. [all data]

Capková and Fried, 1964
Capková, A.; Fried, V., Gleichgewicht flüssigkeit-dampf im system tetrachlorsilan-trimethylchlorsilan, Collect. Czech. Chem. Commun., 1964, 29, 2, 336-340, https://doi.org/10.1135/cccc19640336 . [all data]

Jenkins and Chambers, 1954
Jenkins, Arthur C.; Chambers, George F., Vapor Pressures of Silicon Compounds, Ind. Eng. Chem., 1954, 46, 11, 2367-2369, https://doi.org/10.1021/ie50539a043 . [all data]

Kearby, 1936
Kearby, K., The Vapor Pressure of Silicon Tetrachloride, J. Am. Chem. Soc., 1936, 58, 2, 374-375, https://doi.org/10.1021/ja01293a503 . [all data]

Jain and Yadav, 1973, 2
Jain, D.V.S.; Yadav, O.P., Thermodynamics of n-Alkane Solutions: Part VIII - Vapour Pressures and Excess Free Energies for the SiCl4/n-Hexane System, Indian J. Chem., 1973, 11, 28-30. [all data]

Balk and Dong, 1964
Balk, P.; Dong, D., The Vapor Pressures of Silicon Tetrachloride and Germanium Tetrachloride below Their Melting Points, J. Phys. Chem., 1964, 68, 4, 960-962, https://doi.org/10.1021/j100786a507 . [all data]

Devyatykh, Guesev, et al., 1985
Devyatykh, G.G.; Guesev, A.V.; Gibin, A.M.; Zhernenkov, N.V.; Zakharov, L.M.; Antipin, M.Yu.; Struchov, Yu.M.T., Russ. J. Inorg. Chem., 1985, 30, 780. [all data]


Notes

Go To: Top, Phase change data, References