Nitrous oxide

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Nitric oxide anion + Nitrous oxide = (Nitric oxide anion • Nitrous oxide)

By formula: NO- + N2O = (NO- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°60. ± 100.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°62.3J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=32.2 kJ/mol; M

NO2+ + Nitrous oxide = (NO2+ • Nitrous oxide)

By formula: NO2+ + N2O = (NO2+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°59.0kJ/molEICameron, Aitken, et al., 1994gas phase; M
ΔrH°72.8kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrH°55. ± 3.kJ/molDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol; M
ΔrH°54.8kJ/molPILinn and Ng, 1981gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°51.9J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol; M

Oxygen cation + Nitrous oxide = (Oxygen cation • Nitrous oxide)

By formula: O2+ + N2O = (O2+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°56.1kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrH°45. ± 2.kJ/molDTIllies, 1988gas phase; ΔrH(0 K)=45.2 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°64.0J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=45.2 kJ/mol; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
37.200.FAAdams and Bohme, 1970gas phase; switching reaction(O2+)O2; M

(Iodide • 2Nitrous oxide) + Nitrous oxide = (Iodide • 3Nitrous oxide)

By formula: (I- • 2N2O) + N2O = (I- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°13.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°63.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Nitric oxide anion • Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 2Nitrous oxide)

By formula: (NO- • N2O) + N2O = (NO- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°24.7 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
ΔrH°19.2kJ/molN/ACoe, Snodgrass, et al., 1987gas phase; B
ΔrH°23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
ΔrH°30.kJ/molPESCoe, Snodgrass, et al., 1986gas phase; D(N2O)2 not accounted for; M
Quantity Value Units Method Reference Comment
ΔrG°-4.2 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 2Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 3Nitrous oxide)

By formula: (NO- • 2N2O) + N2O = (NO- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.8 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
ΔrH°21.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-5.0 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Iodide • Nitrous oxide) + Nitrous oxide = (Iodide • 2Nitrous oxide)

By formula: (I- • N2O) + N2O = (I- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°12. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°14. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.4J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Iodide + Nitrous oxide = (Iodide • Nitrous oxide)

By formula: I- + N2O = (I- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°16. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.0J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

HN2O+ + Nitrous oxide = (HN2O+ • Nitrous oxide)

By formula: HN2O+ + N2O = (HN2O+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°69.9kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrH°86.2kJ/molPHPMSSzulejko and McMahon, 1992gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°132.J/mol*KPHPMSSzulejko and McMahon, 1992gas phase; M

(Oxygen anion • 2Nitrous oxide) + Nitrous oxide = (Oxygen anion • 3Nitrous oxide)

By formula: (O2- • 2N2O) + N2O = (O2- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°26.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-3. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion • 3Nitrous oxide) + Nitrous oxide = (Oxygen anion • 4Nitrous oxide)

By formula: (O2- • 3N2O) + N2O = (O2- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°23.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-6.3 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion • 4Nitrous oxide) + Nitrous oxide = (Oxygen anion • 5Nitrous oxide)

By formula: (O2- • 4N2O) + N2O = (O2- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°22.2 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-7.9 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion • 5Nitrous oxide) + Nitrous oxide = (Oxygen anion • 6Nitrous oxide)

By formula: (O2- • 5N2O) + N2O = (O2- • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°20.9 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-9.2 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 2Nitrous oxide) + Nitrous oxide = (O- • 3Nitrous oxide)

By formula: (O- • 2N2O) + N2O = (O- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°22.6 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-4. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 3Nitrous oxide) + Nitrous oxide = (O- • 4Nitrous oxide)

By formula: (O- • 3N2O) + N2O = (O- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-8.4 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 4Nitrous oxide) + Nitrous oxide = (O- • 5Nitrous oxide)

By formula: (O- • 4N2O) + N2O = (O- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-9.6 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 5Nitrous oxide) + Nitrous oxide = (O- • 6Nitrous oxide)

By formula: (O- • 5N2O) + N2O = (O- • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.3 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-11. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 6Nitrous oxide) + Nitrous oxide = (O- • 7Nitrous oxide)

By formula: (O- • 6N2O) + N2O = (O- • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.3 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-14. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • Nitrous oxide) + Nitrous oxide = (O- • 2Nitrous oxide)

By formula: (O- • N2O) + N2O = (O- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°22.6 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-1. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion • Nitrous oxide) + Nitrous oxide = (Oxygen anion • 2Nitrous oxide)

By formula: (O2- • N2O) + N2O = (O2- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°36.4 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

Oxygen anion + Nitrous oxide = (Oxygen anion • Nitrous oxide)

By formula: O2- + N2O = (O2- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°<56.90kJ/molIMRBAdams and Bohme, 1970gas phase; N2O..O2- + O2 -> O4- + N2O; B
ΔrH°37.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

(Nitric oxide anion • 3Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 4Nitrous oxide)

By formula: (NO- • 3N2O) + N2O = (NO- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°20.9 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
ΔrH°19.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-5.0 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 4Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 5Nitrous oxide)

By formula: (NO- • 4N2O) + N2O = (NO- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°17.6 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
ΔrH°19.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-6.3 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Hydronium cation • 3Nitrous oxide) + Nitrous oxide = (Hydronium cation • 4Nitrous oxide)

By formula: (H3O+ • 3N2O) + N2O = (H3O+ • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M

(NO2+ • 5Nitrous oxide) + Nitrous oxide = (NO2+ • 6Nitrous oxide)

By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°16.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M

(HN2O+ • 5Nitrous oxide) + Nitrous oxide = (HN2O+ • 6Nitrous oxide)

By formula: (HN2O+ • 5N2O) + N2O = (HN2O+ • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°130.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M

(Chlorine anion • 4Nitrous oxide) + Nitrous oxide = (Chlorine anion • 5Nitrous oxide)

By formula: (Cl- • 4N2O) + N2O = (Cl- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Fluorine anion • 6Nitrous oxide) + Nitrous oxide = (Fluorine anion • 7Nitrous oxide)

By formula: (F- • 6N2O) + N2O = (F- • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°14.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(NO2+ • 2Nitrous oxide) + Nitrous oxide = (NO2+ • 3Nitrous oxide)

By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°12.kJ/molEICameron, Aitken, et al., 1994gas phase; M
ΔrH°23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ • Nitrous oxide) + Nitrous oxide = (NO2+ • 2Nitrous oxide)

By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.kJ/molEICameron, Aitken, et al., 1994gas phase; M
ΔrH°24.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Nitric oxide anion • 5Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 6Nitrous oxide)

By formula: (NO- • 5N2O) + N2O = (NO- • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°18.4 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M,M
Quantity Value Units Method Reference Comment
ΔrG°-7.9 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 6Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 7Nitrous oxide)

By formula: (NO- • 6N2O) + N2O = (NO- • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°17.6 ± 1.3kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M,M
Quantity Value Units Method Reference Comment
ΔrG°-11. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

Methyl cation + Nitrous oxide = (Methyl cation • Nitrous oxide)

By formula: CH3+ + N2O = (CH3+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°221.kJ/molPHPMSMcMahon, Heinis, et al., 1988gas phase; switching reaction(CH3+)N2, Entropy change calculated or estimated, uses MCA(N2) = 202. kJ/mol; Foster, Williamson, et al., 1974; M

(Iodide • 10Nitrous oxide) + Nitrous oxide = (Iodide • 11Nitrous oxide)

By formula: (I- • 10N2O) + N2O = (I- • 11N2O)

Quantity Value Units Method Reference Comment
ΔrH°4.2 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 11Nitrous oxide) + Nitrous oxide = (Iodide • 12Nitrous oxide)

By formula: (I- • 11N2O) + N2O = (I- • 12N2O)

Quantity Value Units Method Reference Comment
ΔrH°5.4 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 9Nitrous oxide) + Nitrous oxide = (Iodide • 10Nitrous oxide)

By formula: (I- • 9N2O) + N2O = (I- • 10N2O)

Quantity Value Units Method Reference Comment
ΔrH°7.5 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 3Nitrous oxide) + Nitrous oxide = (Iodide • 4Nitrous oxide)

By formula: (I- • 3N2O) + N2O = (I- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°12. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 4Nitrous oxide) + Nitrous oxide = (Iodide • 5Nitrous oxide)

By formula: (I- • 4N2O) + N2O = (I- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 5Nitrous oxide) + Nitrous oxide = (Iodide • 6Nitrous oxide)

By formula: (I- • 5N2O) + N2O = (I- • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°9.6 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 6Nitrous oxide) + Nitrous oxide = (Iodide • 7Nitrous oxide)

By formula: (I- • 6N2O) + N2O = (I- • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°9.2 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 7Nitrous oxide) + Nitrous oxide = (Iodide • 8Nitrous oxide)

By formula: (I- • 7N2O) + N2O = (I- • 8N2O)

Quantity Value Units Method Reference Comment
ΔrH°8.8 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 8Nitrous oxide) + Nitrous oxide = (Iodide • 9Nitrous oxide)

By formula: (I- • 8N2O) + N2O = (I- • 9N2O)

Quantity Value Units Method Reference Comment
ΔrH°10. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(N2O2- • 4294967295Nitrous oxide) + Nitrous oxide = N2O2-

By formula: (N2O2- • 4294967295N2O) + N2O = N2O2-

Quantity Value Units Method Reference Comment
ΔrH°96.7 ± 5.0kJ/molN/ALi and Continetti, 2002gas phase; B
ΔrH°135.1 ± 2.9kJ/molLPDOsboen, Leahy, et al., 1996gas phase; Affinity at 0 K; B

(HO- • 3Nitrous oxide) + Nitrous oxide = (HO- • 4Nitrous oxide)

By formula: (HO- • 3N2O) + N2O = (HO- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°>30. ± 140.kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.981 eV. Affinity is EA difference with next lower +0.08 eV f; B

(HO- • 4Nitrous oxide) + Nitrous oxide = (HO- • 5Nitrous oxide)

By formula: (HO- • 4N2O) + N2O = (HO- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°>20. ± 230.kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 3.146 eV. Affinity is EA difference with next lower +0.08 eV f; B

(HO- • 2Nitrous oxide) + Nitrous oxide = (HO- • 3Nitrous oxide)

By formula: (HO- • 2N2O) + N2O = (HO- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°28.9kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.761 eV. Affinity is EA difference with next lower +0.08 eV f; B

(HO- • Nitrous oxide) + Nitrous oxide = (HO- • 2Nitrous oxide)

By formula: (HO- • N2O) + N2O = (HO- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°32.6kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.485 eV. Affinity is EA difference with next lower +0.08 eV f; B

(Chlorine anion • 2Nitrous oxide) + Nitrous oxide = (Chlorine anion • 3Nitrous oxide)

By formula: (Cl- • 2N2O) + N2O = (Cl- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°21. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°83.7J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Chlorine anion • 3Nitrous oxide) + Nitrous oxide = (Chlorine anion • 4Nitrous oxide)

By formula: (Cl- • 3N2O) + N2O = (Cl- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°87.4J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • 2Nitrous oxide) + Nitrous oxide = (Fluorine anion • 3Nitrous oxide)

By formula: (F- • 2N2O) + N2O = (F- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°35. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°98.7J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S., Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O, J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524 . [all data]

Illies, 1988
Illies, A.J., Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures, J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037 . [all data]

Cameron, Aitken, et al., 1994
Cameron, B.R.; Aitken, C.G.; Harland, P.W., Appearence Energies of Small Cluster Ions and their Fragments, J. Chem. Soc. Faraday Trans., 1994, 90, 7, 935, https://doi.org/10.1039/ft9949000935 . [all data]

Linn and Ng, 1981
Linn, S.H.; Ng, C.Y., Photoionization Study of CO2, N2O Dimers and Clusters, J. Chem. Phys., 1981, 75, 10, 4921, https://doi.org/10.1063/1.441931 . [all data]

Adams and Bohme, 1970
Adams, N.G.; Bohme, D., Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-, J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

Hendricks, de Clercq, et al., 2002
Hendricks, J.H.; de Clercq, H.L.; Freidhoff, C.B.; Arnold, S.T.; Eaton, J.G.; Fancher, C.; Lyapustina, S.A.; S., Anion solvation at the microscopic level: Photoelectron spectroscopy of the solvated anion clusters, NO-(Y)(n), where Y=Ar, Kr, Xe, N2O, H2S, NH3, H2O, and C2H4(OH)(2), J. Chem. Phys., 2002, 116, 18, 7926-7938, https://doi.org/10.1063/1.1457444 . [all data]

Coe, Snodgrass, et al., 1987
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H., Photoelectron spectroscopy of the negative cluster ions, NO-(N2O)n=1,2, J. Chem. Phys., 1987, 87, 4302. [all data]

Hiraoka, Fujimaki, et al., 1994, 2
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Gas-phase clustering reactions of O2(-), NO-, and O- with N2O: Isomeric structures for (NO-N2O)(-), J. Phys. Chem., 1994, 98, 34, 8295, https://doi.org/10.1021/j100085a006 . [all data]

Coe, Snodgrass, et al., 1986
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H., Negative ion photoelectron spectroscopy of N2O- and (N2O)2-, Chem. Phys. Lett., 1986, 124, 274. [all data]

Szulejko and McMahon, 1992
Szulejko, J.; McMahon, T.B., personal communication, 1992. [all data]

McMahon, Heinis, et al., 1988
McMahon, T.; Heinis, T.; Nicol, G.; Hovey, J.K.; Kebarle, P., Methyl Cation Affinities, J. Am. Chem. Soc., 1988, 110, 23, 7591, https://doi.org/10.1021/ja00231a002 . [all data]

Foster, Williamson, et al., 1974
Foster, M.S.; Williamson, A.D.; Beauchamp, J.L., Photoionization mass spectrometry of trans-azomethane, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 429. [all data]

Li and Continetti, 2002
Li, R.J.; Continetti, R.E., Studies of the excited state dynamics of N2O2 by dissociative photodetachment of N2O2-, J. Phys. Chem. A, 2002, 106, 7, 1183-1189, https://doi.org/10.1021/jp013330u . [all data]

Osboen, Leahy, et al., 1996
Osboen, D.L.; Leahy, D.J.; Cyr, D.R.; Neumark, D.M., Photodissociation Spectroscopy and Dynamics of the N2O2- Anion, J. Chem. Phys., 1996, 104, 13, 5026, https://doi.org/10.1063/1.471132 . [all data]

Kim, Wenthold, et al., 1998
Kim, J.B.; Wenthold, P.G.; Lineberger, W.C., Photoelectron spectroscopy of OH-(N2O)(n=1-5), J. Chem. Phys., 1998, 108, 3, 830-837, https://doi.org/10.1063/1.475447 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, References