BrCl2 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas>-161.83kcal/molTherLee, Smith, et al., 1979Computations put dHaff ca. 32 kcal/mol

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

BrCl2- + bromine chloride = (BrCl2- • bromine chloride)

By formula: BrCl2- + BrCl = (BrCl2- • BrCl)

Quantity Value Units Method Reference Comment
Δr<111.00kcal/molPDisLee, Smith, et al., 1979gas phase; Computations put dHaff ca. 32 kcal/mol
Δr38.10kcal/molN/ACheck, Faust, et al., 2001gas phase; FeBO2-(s); ; ΔS(EA)=-9.1
Quantity Value Units Method Reference Comment
Δr26.60kcal/molN/ACheck, Faust, et al., 2001gas phase; FeBO2-(s); ; ΔS(EA)=-9.1

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Reference Comment
4.863808Check, Faust, et al., 2001FeBO2-(s); ; ΔS(EA)=-9.1

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

BrCl2- + bromine chloride = (BrCl2- • bromine chloride)

By formula: BrCl2- + BrCl = (BrCl2- • BrCl)

Quantity Value Units Method Reference Comment
Δr<111.00kcal/molPDisLee, Smith, et al., 1979gas phase; Computations put dHaff ca. 32 kcal/mol
Δr38.10kcal/molN/ACheck, Faust, et al., 2001gas phase; FeBO2-(s); ; ΔS(EA)=-9.1
Quantity Value Units Method Reference Comment
Δr26.60kcal/molN/ACheck, Faust, et al., 2001gas phase; FeBO2-(s); ; ΔS(EA)=-9.1

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee, Smith, et al., 1979
Lee, L.C.; Smith, G.P.; Moseley, J.T.; Cosby, P.C.; Guest, J.A., Photodissociation and photodetachment of Cl2-, ClO-, Cl3-, and BrCl2-, J. Chem. Phys., 1979, 70, 3237. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]


Notes

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