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Me2BCH2 anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.84 ± 0.34D-EAMurphy and Beauchamp, 1976Between AsH3,PH3; value altered from reference due to change in acidity scale

Protonation reactions

C3H8B- + Hydrogen cation = Borane, trimethyl-

By formula: C3H8B- + H+ = C3H9B

Quantity Value Units Method Reference Comment
Deltar1532. ± 26.kJ/molG+TSMurphy and Beauchamp, 1976gas phase; Between AsH3,PH3; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar1502. ± 25.kJ/molIMRBMurphy and Beauchamp, 1976gas phase; Between AsH3,PH3; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Murphy and Beauchamp, 1976
Murphy, M.K.; Beauchamp, J.L., Acid-base properties and gas-phase ion chemistry of (CH3)3B, J. Am. Chem. Soc., 1976, 98, 1433. [all data]


Notes

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