MnF3..F anion
- Formula: F4Mn-
- Molecular weight: 130.932206
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -1438. ± 25. | kJ/mol | Ther | Boltalina, Borshchevskii, et al., 1992 | Critical review; value altered from reference due to conversion from electron convention to ion convention |
| ΔfH°gas | -1460. ± 59. | kJ/mol | TDEq | Korobov, Chilingarov, et al., 1984 | Fluoride Affinity: 18.9 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 5.60 ± 0.40 | R-A | Boltalina, Borshchevskii, et al., 1992 | Critical review; value altered from reference due to conversion from electron convention to ion convention |
| 5.1 ± 1.5 | R-A | Chilingarov, Korobov, et al., 1984 | Fluoride Affinity: 17.2±0.7 kcal < AlF3.; value altered from reference due to conversion from electron convention to ion convention |
| 5.230 ± 0.030 | R-A | Korobov, Chilingarov, et al., 1984 | Fluoride Affinity: 18.9 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N.,
Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase,
Russ. J. Phys. Chem., 1992, 66, 1223. [all data]
Korobov, Chilingarov, et al., 1984
Korobov, M.V.; Chilingarov, N.S.; Igolkina, N.A.; Nikitin, M.I.; Sidorov, L.N.,
Molecules with a high electron affinity. Negative ions in the saturated vapor of the platinum-manganese trifluoride system,
Russ. J. Phys. Chem., 1984, 58, 1368. [all data]
Chilingarov, Korobov, et al., 1984
Chilingarov, N.S.; Korobov, M.V.; Sidirov, L.N.; Mitkin, V.N.; Shipachev, V.A.; Zemskov, S.V.,
Electron affinity of rhodium tetrafluoride,
J. Chem. Thermodyn., 1984, 16, 965. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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