FeF2..FeF3 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-414. ± 10.kcal/molTherSidirov, Borshchevsky, et al., 1986value altered from reference due to conversion from electron convention to ion convention

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

F3Fe- + F2Fe = F5Fe2-

By formula: F3Fe- + F2Fe = F5Fe2-

Quantity Value Units Method Reference Comment
Δr48.3 ± 8.8kcal/molTDEqSidirov, Borshchevsky, et al., 1986gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr48.1 ± 1.0kcal/molTDAsSorokin, Sidorov, et al., 1981gas phase; ΔHf(A-) at 0 K; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.80 ± 0.40R-ASidirov, Borshchevsky, et al., 1986value altered from reference due to conversion from electron convention to ion convention

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

F3Fe- + F2Fe = F5Fe2-

By formula: F3Fe- + F2Fe = F5Fe2-

Quantity Value Units Method Reference Comment
Δr48.3 ± 8.8kcal/molTDEqSidirov, Borshchevsky, et al., 1986gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr48.1 ± 1.0kcal/molTDAsSorokin, Sidorov, et al., 1981gas phase; ΔHf(A-) at 0 K; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sidirov, Borshchevsky, et al., 1986
Sidirov, L.N.; Borshchevsky, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Skokan, E.V., Electron affinities of gaseous iron fluorides and dimers, Int. J. Mass Spectrom. Ion Processes, 1986, 73, 1. [all data]

Sorokin, Sidorov, et al., 1981
Sorokin, I.D.; Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V., Mass-spectrometric determination of the enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. V. Heats of formation of FeF3- and FeF4-, Int. J. Mass Spectrom. Ion Phys., 1981, 41, 45. [all data]


Notes

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