Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

CF3CO anion


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2F3O- + Hydrogen cation = C2HF3O

By formula: C2F3O- + H+ = C2HF3O

Quantity Value Units Method Reference Comment
Deltar>1623. ± 17.kJ/molD-EAHarland and Thynne, 1970gas phase; From (CF3)2CO. Values unreasonable: «DELTA»Hf(CF3CO-)must be less than «DELTA»Hf(CF3-+CO)=-181. G3MP2B3 EA = 1.6 eV
Quantity Value Units Method Reference Comment
Deltar>1590. ± 17.kJ/molH-TSHarland and Thynne, 1970gas phase; From (CF3)2CO. Values unreasonable: «DELTA»Hf(CF3CO-)must be less than «DELTA»Hf(CF3-+CO)=-181. G3MP2B3 EA = 1.6 eV

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Harland and Thynne, 1970
Harland, P.; Thynne, J.C.J., Positive and negative ion formation in hexafluoroacetone by electron impact, J. Phys. Chem., 1970, 74, 52. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References