PhSCH2 anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C7H7S- + Hydrogen cation = Benzene, (methylthio)-

By formula: C7H7S- + H+ = C7H8S

Quantity Value Units Method Reference Comment
Δr1596. ± 8.8kJ/molG+TSIngemann and Nibbering, 1985gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr1566. ± 8.4kJ/molIMREIngemann and Nibbering, 1985gas phase; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ingemann and Nibbering, 1985
Ingemann, S.; Nibbering, N.M.M., Gas phase chemistry of alpha-thio carbanions, Can. J. Chem., 1985, 62, 2273. [all data]


Notes

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