CCl2F anion


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CCl2F- + Hydrogen cation = Fluorodichloromethane

By formula: CCl2F- + H+ = CHCl2F

Quantity Value Units Method Reference Comment
Δr1503.6kJ/molAcidPoutsma, Paulino, et al., 1997gas phase
Δr1507. ± 8.8kJ/molG+TSPoutsma, Paulino, et al., 1997gas phase
Δr<1506. ± 20.kJ/molD-EAIllenberger, Baumgartel, et al., 1979gas phase; From CF2Cl2
Quantity Value Units Method Reference Comment
Δr1471.2 ± 2.5kJ/molH-TSPoutsma, Paulino, et al., 1997gas phase
Δr1475. ± 8.4kJ/molIMRBPoutsma, Paulino, et al., 1997gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CCl2F- + Hydrogen cation = Fluorodichloromethane

By formula: CCl2F- + H+ = CHCl2F

Quantity Value Units Method Reference Comment
Δr1503.6kJ/molAcidPoutsma, Paulino, et al., 1997gas phase
Δr1507. ± 8.8kJ/molG+TSPoutsma, Paulino, et al., 1997gas phase
Δr<1506. ± 20.kJ/molD-EAIllenberger, Baumgartel, et al., 1979gas phase; From CF2Cl2
Quantity Value Units Method Reference Comment
Δr1471.2 ± 2.5kJ/molH-TSPoutsma, Paulino, et al., 1997gas phase
Δr1475. ± 8.4kJ/molIMRBPoutsma, Paulino, et al., 1997gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Poutsma, Paulino, et al., 1997
Poutsma, J.C.; Paulino, J.A.; Squires, R.R., Absolute Heats of Formation of CHCl, CHF, and CClF. A Gas-Phase Experimental and G2 Theoretical Study., J. Phys. Chem. A, 1997, 101, 29, 5327, https://doi.org/10.1021/jp970778f . [all data]

Illenberger, Baumgartel, et al., 1979
Illenberger, T.; Baumgartel, H.; Scheunemann, H., Negative Ion Formation in CF2Cl2, CF3Cl, and CFCl3 Following Low Energy (0-10eV) Impact with Near Monoenergetic Electrons, Chem. Phys., 1979, 37, 1, 21, https://doi.org/10.1016/0301-0104(79)80003-8 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References