CCl2F anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CCl2F- + Hydrogen cation = Fluorodichloromethane

By formula: CCl2F- + H+ = CHCl2F

Quantity Value Units Method Reference Comment
Δr1503.6kJ/molAcidPoutsma, Paulino, et al., 1997gas phase
Δr1507. ± 8.8kJ/molG+TSPoutsma, Paulino, et al., 1997gas phase
Δr<1506. ± 20.kJ/molD-EAIllenberger, Baumgartel, et al., 1979gas phase; From CF2Cl2
Quantity Value Units Method Reference Comment
Δr1471.2 ± 2.5kJ/molH-TSPoutsma, Paulino, et al., 1997gas phase
Δr1475. ± 8.4kJ/molIMRBPoutsma, Paulino, et al., 1997gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Poutsma, Paulino, et al., 1997
Poutsma, J.C.; Paulino, J.A.; Squires, R.R., Absolute Heats of Formation of CHCl, CHF, and CClF. A Gas-Phase Experimental and G2 Theoretical Study., J. Phys. Chem. A, 1997, 101, 29, 5327, https://doi.org/10.1021/jp970778f . [all data]

Illenberger, Baumgartel, et al., 1979
Illenberger, T.; Baumgartel, H.; Scheunemann, H., Negative Ion Formation in CF2Cl2, CF3Cl, and CFCl3 Following Low Energy (0-10eV) Impact with Near Monoenergetic Electrons, Chem. Phys., 1979, 37, 1, 21, https://doi.org/10.1016/0301-0104(79)80003-8 . [all data]


Notes

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