MeSCH2 anion
- Formula: C2H5S-
- Molecular weight: 61.127
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C2H5S- + =
By formula: C2H5S- + H+ = C2H6S
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 390.2 ± 1.5 | kcal/mol | D-EA | Moran and Ellison, 1988 | gas phase |
| ΔrH° | 393.2 ± 2.1 | kcal/mol | G+TS | Ingemann and Nibbering, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 383.0 ± 1.7 | kcal/mol | H-TS | Moran and Ellison, 1988 | gas phase |
| ΔrG° | 386.0 ± 2.0 | kcal/mol | IMRE | Ingemann and Nibbering, 1985 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Moran and Ellison, 1988
Moran, S.; Ellison, G.B.,
Photoelectron Spectroscopy of Sulfur Ions,
J. Phys. Chem., 1988, 92, 7, 1794, https://doi.org/10.1021/j100318a021
. [all data]
Ingemann and Nibbering, 1985
Ingemann, S.; Nibbering, N.M.M.,
Gas phase chemistry of alpha-thio carbanions,
Can. J. Chem., 1985, 62, 2273. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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