Me2NCH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H8N- + Hydrogen cation = Methylamine, N,N-dimethyl-

By formula: C3H8N- + H+ = C3H9N

Quantity Value Units Method Reference Comment
Δr>1699.6 ± 2.5kJ/molG+TSMacKay and Bohme, 1978gas phase; Computations put dHacid ca. 412 kcal/mol
Quantity Value Units Method Reference Comment
Δr>1665.2kJ/molIMRBMacKay and Bohme, 1978gas phase; Computations put dHacid ca. 412 kcal/mol

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C3H8N- + Hydrogen cation = Methylamine, N,N-dimethyl-

By formula: C3H8N- + H+ = C3H9N

Quantity Value Units Method Reference Comment
Δr>1699.6 ± 2.5kJ/molG+TSMacKay and Bohme, 1978gas phase; Computations put dHacid ca. 412 kcal/mol
Quantity Value Units Method Reference Comment
Δr>1665.2kJ/molIMRBMacKay and Bohme, 1978gas phase; Computations put dHacid ca. 412 kcal/mol

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

MacKay and Bohme, 1978
MacKay, G.I.; Bohme, D.K., Proton-Transfer Reactions in Nitromethane at 297K, Int. J. Mass Spectrom. Ion Phys., 1978, 26, 4, 327, https://doi.org/10.1016/0020-7381(78)80052-7 . [all data]


Notes

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