Me2NCH2 anion
- Formula: C3H8N-
- Molecular weight: 58.1029
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C3H8N- + =
By formula: C3H8N- + H+ = C3H9N
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | >1699.6 ± 2.5 | kJ/mol | G+TS | MacKay and Bohme, 1978 | gas phase; Computations put dHacid ca. 412 kcal/mol |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | >1665.2 | kJ/mol | IMRB | MacKay and Bohme, 1978 | gas phase; Computations put dHacid ca. 412 kcal/mol |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
C3H8N- + =
By formula: C3H8N- + H+ = C3H9N
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | >1699.6 ± 2.5 | kJ/mol | G+TS | MacKay and Bohme, 1978 | gas phase; Computations put dHacid ca. 412 kcal/mol |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | >1665.2 | kJ/mol | IMRB | MacKay and Bohme, 1978 | gas phase; Computations put dHacid ca. 412 kcal/mol |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
MacKay and Bohme, 1978
MacKay, G.I.; Bohme, D.K.,
Proton-Transfer Reactions in Nitromethane at 297K,
Int. J. Mass Spectrom. Ion Phys., 1978, 26, 4, 327, https://doi.org/10.1016/0020-7381(78)80052-7
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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