HCF2 anion
- Formula: CHF2-
- Molecular weight: 51.0160
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
CHF2- + =
By formula: CHF2- + H+ = CH2F2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 389.0 ± 3.5 | kcal/mol | CIDT | Graul and Squires, 1990 | gas phase; G2 calculations( Lee, Dyke, et al., 1998) predict ΔHacid = 399 kcal/mol |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 381.2 ± 3.6 | kcal/mol | H-TS | Graul and Squires, 1990 | gas phase; G2 calculations( Lee, Dyke, et al., 1998) predict ΔHacid = 399 kcal/mol |
| ΔrG° | 379.0 ± 6.0 | kcal/mol | IMRB | Sullivan, 1977 | gas phase |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Graul and Squires, 1990
Graul, S.T.; Squires, R.R.,
Gas-Phase Acidities Derived from Threshold Energies for Activated Reactions,
J. Am. Chem. Soc., 1990, 112, 7, 2517, https://doi.org/10.1021/ja00163a007
. [all data]
Lee, Dyke, et al., 1998
Lee, E.P.F.; Dyke, J.M.; Mayhew, C.A.,
Study of the OH-+CH2F2 reaction by selected ion flow tube experiments and ab initio calculations,
J. Phys. Chem. A, 1998, 102, 43, 8349-8354, https://doi.org/10.1021/jp982224y
. [all data]
Sullivan, 1977
Sullivan, S.A.,
Thesis, Cal. Inst. Tech. thesis,, 1977. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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