MeCH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H5- + Hydrogen cation = Ethane

By formula: C2H5- + H+ = C2H6

Quantity Value Units Method Reference Comment
Δr1758. ± 8.4kJ/molBranDePuy, Gronert, et al., 1989gas phase
Δr1761. ± 8.4kJ/molBranDePuy, Bierbaum, et al., 1984gas phase
Quantity Value Units Method Reference Comment
Δr1723. ± 8.8kJ/molH-TSDePuy, Gronert, et al., 1989gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C2H5- + Hydrogen cation = Ethane

By formula: C2H5- + H+ = C2H6

Quantity Value Units Method Reference Comment
Δr1758. ± 8.4kJ/molBranDePuy, Gronert, et al., 1989gas phase
Δr1761. ± 8.4kJ/molBranDePuy, Bierbaum, et al., 1984gas phase
Quantity Value Units Method Reference Comment
Δr1723. ± 8.8kJ/molH-TSDePuy, Gronert, et al., 1989gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy, Gronert, et al., 1989
DePuy, C.H.; Gronert, S.; Barlow, S.E.; Bierbaum, V.M.; Damrauer, R., The Gas Phase Acidities of the Alkanes, J. Am. Chem. Soc., 1989, 111, 6, 1968, https://doi.org/10.1021/ja00188a003 . [all data]

DePuy, Bierbaum, et al., 1984
DePuy, C.H.; Bierbaum, V.M.; Damrauer, R., Relative Gas-Phase Acidities of the Alkanes, J. Am. Chem. Soc., 1984, 106, 4051. [all data]


Notes

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