CH2=CFCH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H4F- + Hydrogen cation = 2-Fluoropropene

By formula: C3H4F- + H+ = C3H5F

Quantity Value Units Method Reference Comment
Δr1586. ± 13.kJ/molG+TSBartmess and Burnham, 1984gas phase; value altered from reference due to change in acidity scale
Δr1579. ± 8.8kJ/molG+TSMcMahon and Northcott, 1978gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr1559. ± 13.kJ/molIMRBBartmess and Burnham, 1984gas phase; value altered from reference due to change in acidity scale
Δr1551. ± 8.4kJ/molIMRBMcMahon and Northcott, 1978gas phase; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bartmess and Burnham, 1984
Bartmess, J.E.; Burnham, R., Effect of central substituents on the gas phase acidities of propenes, J. Org. Chem., 1984, 49, 1382. [all data]

McMahon and Northcott, 1978
McMahon, T.B.; Northcott, C.J., The Fluoroformate Ion FCO2-: An ICR study of the gas phase lewis acidity of carbon dioxide and related isoelectronic species, Can. J. Chem., 1978, 56, 1068. [all data]


Notes

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