phenalenide anion
- Formula: C13H9-
- Molecular weight: 165.2111
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C13H9- + =
By formula: C13H9- + H+ = C13H10
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1468. ± 16. | kJ/mol | D-EA | Gygax, Peters, et al., 1979 | gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1440. ± 16. | kJ/mol | H-TS | Gygax, Peters, et al., 1979 | gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993 |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 1.07 ± 0.10 | PD | Gygax, Peters, et al., 1979 | BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993 |
Protonation reactions
C13H9- + =
By formula: C13H9- + H+ = C13H10
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1468. ± 16. | kJ/mol | D-EA | Gygax, Peters, et al., 1979 | gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1440. ± 16. | kJ/mol | H-TS | Gygax, Peters, et al., 1979 | gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993 |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Gygax, Peters, et al., 1979
Gygax, R.; Peters, H.L.; Brauman, J.I.,
Photodetachment of electrons from anions of high symmetry. Electron photodetachment spectra of the cycloctatetraenyl and perinaphthenyl anions,
J. Am. Chem. Soc., 1979, 101, 2567. [all data]
Gerst and Rüchardt, 1993
Gerst, M.; Rüchardt, C.,
H-Transferreaktionen mit Phenalen,
Chem. Ber., 1993, 126, 4, 1039, https://doi.org/10.1002/cber.19931260426
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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