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phenalenide anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.07 ± 0.10PDGygax, Peters, et al., 1979BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993

Protonation reactions

C13H9- + Hydrogen cation = 1H-Phenalene

By formula: C13H9- + H+ = C13H10

Quantity Value Units Method Reference Comment
Deltar1468. ± 16.kJ/molD-EAGygax, Peters, et al., 1979gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993
Quantity Value Units Method Reference Comment
Deltar1440. ± 16.kJ/molH-TSGygax, Peters, et al., 1979gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gygax, Peters, et al., 1979
Gygax, R.; Peters, H.L.; Brauman, J.I., Photodetachment of electrons from anions of high symmetry. Electron photodetachment spectra of the cycloctatetraenyl and perinaphthenyl anions, J. Am. Chem. Soc., 1979, 101, 2567. [all data]

Gerst and Rüchardt, 1993
Gerst, M.; Rüchardt, C., H-Transferreaktionen mit Phenalen, Chem. Ber., 1993, 126, 4, 1039, https://doi.org/10.1002/cber.19931260426 . [all data]


Notes

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