fluorenide anion
- Formula: C13H9-
- Molecular weight: 165.2111
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C13H9- + =
By formula: C13H9- + H+ = C13H10
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 350.5 ± 2.0 | kcal/mol | D-EA | Römer, Janaway, et al., 1997 | gas phase |
| ΔrH° | 351.7 ± 2.1 | kcal/mol | G+TS | Taft and Bordwell, 1988 | gas phase |
| ΔrH° | 353.3 ± 2.6 | kcal/mol | G+TS | Cumming and Kebarle, 1978 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 342.7 ± 2.1 | kcal/mol | H-TS | Römer, Janaway, et al., 1997 | gas phase |
| ΔrG° | 344.0 ± 2.0 | kcal/mol | IMRE | Taft and Bordwell, 1988 | gas phase |
| ΔrG° | 345.5 ± 2.0 | kcal/mol | IMRE | Cumming and Kebarle, 1978 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
C13H9- + =
By formula: C13H9- + H+ = C13H10
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 350.5 ± 2.0 | kcal/mol | D-EA | Römer, Janaway, et al., 1997 | gas phase |
| ΔrH° | 351.7 ± 2.1 | kcal/mol | G+TS | Taft and Bordwell, 1988 | gas phase |
| ΔrH° | 353.3 ± 2.6 | kcal/mol | G+TS | Cumming and Kebarle, 1978 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 342.7 ± 2.1 | kcal/mol | H-TS | Römer, Janaway, et al., 1997 | gas phase |
| ΔrG° | 344.0 ± 2.0 | kcal/mol | IMRE | Taft and Bordwell, 1988 | gas phase |
| ΔrG° | 345.5 ± 2.0 | kcal/mol | IMRE | Cumming and Kebarle, 1978 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Römer, Janaway, et al., 1997
Römer, B.; Janaway, G.; Brauman, J.I.,
Cyclopentadienyl, Indenyl, and Fluorenyl Anions: Gas-Phase and Solvation Energy Contributions to Electron Detachment Energies,
J. Am. Chem. Soc., 1997, 119, 9, 2249, https://doi.org/10.1021/ja961947x
. [all data]
Taft and Bordwell, 1988
Taft, R.W.; Bordwell, F.G.,
Structural and Solvent Effects Evaluated from Acidities Measured in Dimethyl Sulfoxide and in the Gas Phase,
Acc. Chem. Res., 1988, 21, 12, 463, https://doi.org/10.1021/ar00156a005
. [all data]
Cumming and Kebarle, 1978
Cumming, J.B.; Kebarle, P.,
Summary of gas phase measurements involving acids AH. Entropy changes in proton transfer reactions involving negative ions. Bond dissociation energies D(A-H) and electron affinities EA(A),
Can. J. Chem., 1978, 56, 1. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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