H(NHCH2CO)4NHCH(CONH2)CH2S- [Gly4CysNH2]


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C11H19N6O5S + Hydrogen cation = C11H20N6O5S

By formula: C11H19N6O5S + H+ = C11H20N6O5S

Quantity Value Units Method Reference Comment
Δr321.9 ± 2.8kcal/molCIDCMorishetti, Huang, et al., 2010gas phase; Acid: (Gly)4CysNH2
Quantity Value Units Method Reference Comment
Δr317.4 ± 2.9kcal/molH-TSMorishetti, Huang, et al., 2010gas phase; Acid: (Gly)4CysNH2

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C11H19N6O5S + Hydrogen cation = C11H20N6O5S

By formula: C11H19N6O5S + H+ = C11H20N6O5S

Quantity Value Units Method Reference Comment
Δr321.9 ± 2.8kcal/molCIDCMorishetti, Huang, et al., 2010gas phase; Acid: (Gly)4CysNH2
Quantity Value Units Method Reference Comment
Δr317.4 ± 2.9kcal/molH-TSMorishetti, Huang, et al., 2010gas phase; Acid: (Gly)4CysNH2

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Morishetti, Huang, et al., 2010
Morishetti, K.K.; Huang, B.D.; Yates, J.M.; Ren, J.H., Gas-Phase Acidities of Cysteine-Polyglycine Peptides: The Effect of the Cysteine Position, J. Am. Soc. Mass Spectrom., 2010, 21, 4, 603-614, https://doi.org/10.1016/j.jasms.2009.12.008 . [all data]


Notes

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