1-Ph-cyclopropanide anion
- Formula: C9H9-
- Molecular weight: 117.1683
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C9H9- + =
By formula: C9H9- + H+ = C9H10
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 389.8 ± 3.1 | kcal/mol | G+TS | Chou, Dahlke, et al., 1993 | gas phase; Between water, furan |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 382.1 ± 3.0 | kcal/mol | IMRB | Chou, Dahlke, et al., 1993 | gas phase; Between water, furan |
| ΔrG° | 384.0 ± 3.0 | kcal/mol | IMRB | Andrist, DePuy, et al., 1984 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chou, Dahlke, et al., 1993
Chou, P.K.; Dahlke, G.D.; Kass, S.R.,
Unimolecular Rearrangements of Carbanions in the Gas Phase .2. Cyclopropyl Anions,
J. Chem. Soc. Chem. Comm., 1993, 115, 1, 315, https://doi.org/10.1021/ja00054a045
. [all data]
Andrist, DePuy, et al., 1984
Andrist, A.H.; DePuy, C.H.; Squires, R.R.,
Structures of ssomeric anions in the gas phase: Arylallyl and arylcyclopropyl anions,
J. Am. Chem. Soc., 1984, 106, 845. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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