ClCH2PH anion

Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH3ClP- + Hydrogen cation = CH4ClP

By formula: CH3ClP- + H+ = CH4ClP

Quantity Value Units Method Reference Comment
ΔrG°326.08kcal/molIMREHurtado, Yanez, et al., 2009gas phase; Anion is dissociative in regard to Cl- loss. G3MP2B3: Cl- loss endo by 8 kcal/mol

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CH3ClP- + Hydrogen cation = CH4ClP

By formula: CH3ClP- + H+ = CH4ClP

Quantity Value Units Method Reference Comment
ΔrG°326.08kcal/molIMREHurtado, Yanez, et al., 2009gas phase; Anion is dissociative in regard to Cl- loss. G3MP2B3: Cl- loss endo by 8 kcal/mol

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hurtado, Yanez, et al., 2009
Hurtado, M.; Yanez, M.; Herrero, R.; Guerrero, A.; Davalos, J.Z.; Abboud, J.L.M.; Khater, B.; Guillemin, J.C., The Ever-Surprising Chemistry of Boron: Enhanced Acidity of Phosphine center dot Boranes, Chem. Eur. J., 2009, 15, 18, 4622-4629, https://doi.org/10.1002/chem.200802307 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References