CF2=C(CF3)O anion
- Formula: C3F5O-
- Molecular weight: 147.0241
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C3F5O- + =
By formula: C3F5O- + H+ = C3HF5O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1412. ± 18. | kJ/mol | G+TS | Farid and McMahon, 1980 | gas phase; Between FCH2CO2H, HCl; nearer to HCl; value altered from reference due to change in acidity scale |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1384. ± 17. | kJ/mol | IMRB | Farid and McMahon, 1980 | gas phase; Between FCH2CO2H, HCl; nearer to HCl; value altered from reference due to change in acidity scale |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 2.10 ± 0.30 | EIAE | Harland and Thynne, 1970 | From (CF3)2CO |
Protonation reactions
C3F5O- + =
By formula: C3F5O- + H+ = C3HF5O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1412. ± 18. | kJ/mol | G+TS | Farid and McMahon, 1980 | gas phase; Between FCH2CO2H, HCl; nearer to HCl; value altered from reference due to change in acidity scale |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1384. ± 17. | kJ/mol | IMRB | Farid and McMahon, 1980 | gas phase; Between FCH2CO2H, HCl; nearer to HCl; value altered from reference due to change in acidity scale |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Farid and McMahon, 1980
Farid, R.; McMahon, T.B.,
The gas phase acidities of fluorinated acetones. An ICR investigation of the role of fluorine substituents in the stabilization of planar carbanions,
Can. J. Chem., 1980, 58, 2307. [all data]
Harland and Thynne, 1970
Harland, P.; Thynne, J.C.J.,
Positive and negative ion formation in hexafluoroacetone by electron impact,
J. Phys. Chem., 1970, 74, 52. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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