CH2=C(tBu)O anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.755 ± 0.050LPDBrinkman, Berger, et al., 1993 
1.843 ± 0.065PDZimmerman, Reed, et al., 1977 

Protonation reactions

C6H11O- + Hydrogen cation = 2-Butanone, 3,3-dimethyl-

By formula: C6H11O- + H+ = C6H12O

Quantity Value Units Method Reference Comment
Δr369.1 ± 2.3kcal/molD-EABrinkman, Berger, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Δr362.4 ± 2.5kcal/molH-TSBrinkman, Berger, et al., 1993gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brinkman, Berger, et al., 1993
Brinkman, E.A.; Berger, S.; Marks, J.; Brauman, J.I., Molecular Rotation and the Observation of Dipole-Bound States of Anions, J. Chem. Phys., 1993, 99, 10, 7586, https://doi.org/10.1063/1.465688 . [all data]

Zimmerman, Reed, et al., 1977
Zimmerman, A.H.; Reed, K.J.; Brauman, J.I., Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicals, J. Am. Chem. Soc., 1977, 99, 7203. [all data]


Notes

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