CF2=CF2..Cl anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Ethene, tetrafluoro- = C2ClF4-

By formula: Cl- + C2F4 = C2ClF4-

Quantity Value Units Method Reference Comment
Δr>10.00kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN
Quantity Value Units Method Reference Comment
Δr2.55kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN

C2ClF4- + 2Ethene, tetrafluoro- = C4ClF8-

By formula: C2ClF4- + 2C2F4 = C4ClF8-

Quantity Value Units Method Reference Comment
Δr6.60 ± 0.50kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase
Quantity Value Units Method Reference Comment
Δr1.83 ± 0.50kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2ClF4- + 2Ethene, tetrafluoro- = C4ClF8-

By formula: C2ClF4- + 2C2F4 = C4ClF8-

Quantity Value Units Method Reference Comment
Δr6.60 ± 0.50kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase
Quantity Value Units Method Reference Comment
Δr1.83 ± 0.50kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase

Chlorine anion + Ethene, tetrafluoro- = C2ClF4-

By formula: Cl- + C2F4 = C2ClF4-

Quantity Value Units Method Reference Comment
Δr>10.00kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN
Quantity Value Units Method Reference Comment
Δr2.55kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Mochizuki, et al., 2008
Hiraoka, K.; Mochizuki, N.; Wada, A.; Okada, H.; Ichikawa, T.; Asakawa, D.; Yazawa, I., Gas-phase ion/molecule reactions in C2F4, Int. J. Mass Spectrom., 2008, 272, 1, 22-28, https://doi.org/10.1016/j.ijms.2007.12.013 . [all data]

Curtiss, Raghavachari, et al., 7374
Curtiss, L.A.; Raghavachari, K.; Redfern, P.C.; Pople, J.A., Assesment of Gaussian-3 and density Functional Theories for a larger experimental test set, J. Chem. Phys. 112 (2000), 7374. [all data]


Notes

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