PH radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas32.7 ± 8.3kcal/molAcidErvin and Lineberger, 2005 
Δfgas52.0 ± 4.3kcal/molEIAEHalmann and Platzner, 1969From PH3

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

HP- + Hydrogen cation = Phosphino radical

By formula: HP- + H+ = H2P

Quantity Value Units Method Reference Comment
Δr369.8 ± 8.1kcal/molD-EAErvin and Lineberger, 2005gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

HP- + Hydrogen cation = Phosphino radical

By formula: HP- + H+ = H2P

Quantity Value Units Method Reference Comment
Δr369.8 ± 8.1kcal/molD-EAErvin and Lineberger, 2005gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ervin and Lineberger, 2005
Ervin, K.M.; Lineberger, W.C., Photoelectron spectroscopy of phosphorus hydride anions, J. Chem. Phys., 2005, 122, 19, 194303, https://doi.org/10.1063/1.1881153 . [all data]

Halmann and Platzner, 1969
Halmann, M.; Platzner, I., Negative Ions Produced by Electron Capture in Phosphine, J. Phys. Chem., 1969, 73, 12, 4376, https://doi.org/10.1021/j100846a062 . [all data]


Notes

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