CF3H..MeO anion
- Formula: C2H4F3O-
- Molecular weight: 101.0483
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -921.7 ± 5.0 | kJ/mol | Ther | Chabinyc and Brauman, 1998 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
CH3O- + = C2H4F3O-
By formula: CH3O- + CHF3 = C2H4F3O-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 98.3 ± 4.2 | kJ/mol | IMRE | Chabinyc and Brauman, 1998 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 69.5 ± 4.2 | kJ/mol | IMRE | Chabinyc and Brauman, 1998 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chabinyc and Brauman, 1998
Chabinyc, M.L.; Brauman, J.I.,
Acidity, basicity, and the stability of hydrogen bonds: Complexes of RO-+HCF3,
J. Am. Chem. Soc., 1998, 120, 42, 10863-10870, https://doi.org/10.1021/ja9817592
. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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