pF-C6H4CH2O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C7H6FO- + Hydrogen cation = 4-Fluorobenzyl alcohol

By formula: C7H6FO- + H+ = C7H7FO

Quantity Value Units Method Reference Comment
Δr366.0 ± 2.1kcal/molG+TSMustanir, Than, et al., 2005gas phase
Quantity Value Units Method Reference Comment
Δr359.4 ± 2.0kcal/molIMREMustanir, Than, et al., 2005gas phase

C7H6FO- = C8H10FO2-

By formula: C7H6FO- = C8H10FO2-

Quantity Value Units Method Reference Comment
Δr9.40kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.24 ± 0.13D-EAMustanir, Than, et al., 2005 

Protonation reactions

C7H6FO- + Hydrogen cation = 4-Fluorobenzyl alcohol

By formula: C7H6FO- + H+ = C7H7FO

Quantity Value Units Method Reference Comment
Δr366.0 ± 2.1kcal/molG+TSMustanir, Than, et al., 2005gas phase
Quantity Value Units Method Reference Comment
Δr359.4 ± 2.0kcal/molIMREMustanir, Than, et al., 2005gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mustanir, Than, et al., 2005
Mustanir; Than, S.; Mishima, M., Substituent effects on the gas phase acidity of phenylacetylenes and benzyl alcohols, Bull. Chem. Soc. Japan, 2005, 78, 1, 147-153, https://doi.org/10.1246/bcsj.78.147 . [all data]

Mustanir, Matsuoka, et al., 2006
Mustanir; Matsuoka, M.; Mishima, M.; Koch, H., Stability of complexes of phenylacetylides and benzyl alkoxides with methanol in the gas phase. Acid-base correlation in the ionic hydrogen-bond strength, Bull. Chem. Soc. Japan, 2006, 79, 7, 1118-1125, https://doi.org/10.1246/bcsj.79.1118 . [all data]


Notes

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