nC5H11S anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.090 ± 0.020LPDJanousek, Reed, et al., 1980 

Protonation reactions

C5H11S- + Hydrogen cation = 1-Pentanethiol

By formula: C5H11S- + H+ = C5H12S

Quantity Value Units Method Reference Comment
Δr352.5 ± 2.4kcal/molD-EAJanousek, Reed, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Δr346.2 ± 2.5kcal/molH-TSJanousek, Reed, et al., 1980gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Janousek, Reed, et al., 1980
Janousek, B.K.; Reed, K.J.; Brauman, J.I., Electron photodetachment from mercaptyl anions (RS- electron affinities of mercaptyl radicals and the S-H bond strength in mercaptans), J. Am. Chem. Soc., 1980, 102, 3125. [all data]


Notes

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