H2NS anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

H2NS- + Hydrogen cation = H3NS

By formula: H2NS- + H+ = H3NS

Quantity Value Units Method Reference Comment
Δr1493. ± 13.kJ/molG+TSDePuy and Bierbaum, 1981gas phase; Between CF3CH2OH and H2S, comparable to MeSH; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr1467. ± 13.kJ/molIMRBDePuy and Bierbaum, 1981gas phase; Between CF3CH2OH and H2S, comparable to MeSH; value altered from reference due to change in acidity scale
Δr1480. ± 13.kJ/molIMRBBierbaum, Grabowski, et al., 1984gas phase; NH2- + COS ->.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy and Bierbaum, 1981
DePuy, C.H.; Bierbaum, V.M., Gas phase sulfur anions: Synthesis and reactions of H2NS- and related ions, Tetrahedron Lett., 1981, 22, 5129. [all data]

Bierbaum, Grabowski, et al., 1984
Bierbaum, V.M.; Grabowski, J.J.; DePuy, C.H., Gas-phase synthesis and reactions of nitrogen- and sulfur-containing anions, J. Phys. Chem., 1984, 88, 1389. [all data]


Notes

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