(H2O)15..N3 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-882.80kcal/molTherYang, Kiran, et al., 2004Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 6.02±0.08 eV

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

H28N3O14- + 15Water = H30N3O15-

By formula: H28N3O14- + 15H2O = H30N3O15-

Quantity Value Units Method Reference Comment
Δr2.10kcal/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 6.02±0.08 eV

H30N3O15- + 16Water = H32N3O16-

By formula: H30N3O15- + 16H2O = H32N3O16-

Quantity Value Units Method Reference Comment
Δr0.90kcal/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 6.07±0.08 eV

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yang, Kiran, et al., 2004
Yang, X.; Kiran, B.; Wang, X.B.; Wang, L.S.; Mucha, M.; Jungwirth, P., Solvation of the azide anion (N-3(-)) in water clusters and aqueous interfaces: A combined investigation by photoelectron spectroscopy, density functional calculations, and molecular dynamic, J. Phys. Chem. A, 2004, 108, 39, 7820-7826, https://doi.org/10.1021/jp0496396 . [all data]


Notes

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