(H2O)8..N3 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-464.40kcal/molTherYang, Kiran, et al., 2004Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.42±0.08 eV

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

H14N3O7- + 8Water = H16N3O8-

By formula: H14N3O7- + 8H2O = H16N3O8-

Quantity Value Units Method Reference Comment
Δr3.20kcal/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.42±0.08 eV

H16N3O8- + 9Water = H18N3O9-

By formula: H16N3O8- + 9H2O = H18N3O9-

Quantity Value Units Method Reference Comment
Δr3.20kcal/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.55±0.08 eV

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
4.980 ± 0.080LPESYang, Kiran, et al., 2004Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.42±0.08 eV

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

H14N3O7- + 8Water = H16N3O8-

By formula: H14N3O7- + 8H2O = H16N3O8-

Quantity Value Units Method Reference Comment
Δr3.20kcal/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.42±0.08 eV

H16N3O8- + 9Water = H18N3O9-

By formula: H16N3O8- + 9H2O = H18N3O9-

Quantity Value Units Method Reference Comment
Δr3.20kcal/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.55±0.08 eV

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yang, Kiran, et al., 2004
Yang, X.; Kiran, B.; Wang, X.B.; Wang, L.S.; Mucha, M.; Jungwirth, P., Solvation of the azide anion (N-3(-)) in water clusters and aqueous interfaces: A combined investigation by photoelectron spectroscopy, density functional calculations, and molecular dynamic, J. Phys. Chem. A, 2004, 108, 39, 7820-7826, https://doi.org/10.1021/jp0496396 . [all data]


Notes

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