H2O..N3 anion

Formula: H₂N₃O^-
Molecular weight: 60.0359
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Ion clustering data

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Clustering reactions

H₂N₃O^- + 2 = H₄N₃O₂^-

By formula: H₂N₃O^- + 2H₂O = H₄N₃O₂^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	40. ± 390.	kJ/mol	N/A	Yang, Kiran, et al., 2004	gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 3.78±0.06 eV

+ = H₂N₃O^-

By formula: N₃^- + H₂O = H₂N₃O^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	46. ± 75.	kJ/mol	N/A	Yang, Kiran, et al., 2004	gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 3.25±0.03 eV

References

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Yang, Kiran, et al., 2004
Yang, X.; Kiran, B.; Wang, X.B.; Wang, L.S.; Mucha, M.; Jungwirth, P., Solvation of the azide anion (N-3(-)) in water clusters and aqueous interfaces: A combined investigation by photoelectron spectroscopy, density functional calculations, and molecular dynamic, J. Phys. Chem. A, 2004, 108, 39, 7820-7826, https://doi.org/10.1021/jp0496396 . [all data]

Notes

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Symbols used in this document:

Δ_rH° Enthalpy of reaction at standard conditions
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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