(EtNO2)2..EtNO2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CAS Reg. No. 34533-65-8 + 2Ethane, nitro- = C6H15N3O6-

By formula: CAS Reg. No. 34533-65-8 + 2C2H5NO2 = C6H15N3O6-

Quantity Value Units Method Reference Comment
Δr14.60 ± 0.20kcal/molTDAsWincel, 2004gas phase
Quantity Value Units Method Reference Comment
Δr6.30kcal/molTDAsWincel, 2004gas phase

C6H15N3O6- + 3Ethane, nitro- = C8H20N4O8-

By formula: C6H15N3O6- + 3C2H5NO2 = C8H20N4O8-

Quantity Value Units Method Reference Comment
Δr13.60 ± 0.30kcal/molTDAsWincel, 2004gas phase
Quantity Value Units Method Reference Comment
Δr4.70kcal/molTDAsWincel, 2004gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.50 ± 0.20LPESStokes, Bowen, et al., 2008Vertical Detachment Energy: 2.04±0.1 eV

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wincel, 2004
Wincel, H., Gas-phase clustering reactions of NO2-, C2H3NO2-, C2H4NO2-C2H5NO2- and C2H5NO4- with C2H5NO2, Int. J. Mass Spectrom., 2004, 232, 2, 185-194, https://doi.org/10.1016/j.ijms.2004.01.003 . [all data]

Stokes, Bowen, et al., 2008
Stokes, S.T.; Bowen, K.H.; Sommerfeld, T.; Ard, S.; Mirsaleh-Kohan, N.; Steill, J.D.; Compton, R.N., Negative ions of nitroethane and its clusters, J. Chem. Phys., 2008, 129, 6, 064308, https://doi.org/10.1063/1.2965534 . [all data]


Notes

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