3,3-dimethyl-cyclopropenide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C5H7- + Hydrogen cation = Cyclopropene, 3,3-dimethyl-

By formula: C5H7- + H+ = C5H8

Quantity Value Units Method Reference Comment
Δr382.6 ± 1.4kcal/molG+TSFattahi, McCarthy, et al., 2003gas phase; Maybe be ring-opened HCC-C(Me)2- structure
Quantity Value Units Method Reference Comment
Δr374.4 ± 1.3kcal/molIMREFattahi, McCarthy, et al., 2003gas phase; Maybe be ring-opened HCC-C(Me)2- structure

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fattahi, McCarthy, et al., 2003
Fattahi, A.; McCarthy, R.E.; Ahmad, M.R.; Kass, S.R., Why does cyclopropene have the acidity of an acetylene but the bond energy of methane?, J. Am. Chem. Soc., 2003, 125, 38, 11746-11750, https://doi.org/10.1021/ja035725s . [all data]


Notes

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