Et2NO anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.54 ± 0.13D-EABartmess, Basso, et al., 1983See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values

Protonation reactions

C4H10NO- + Hydrogen cation = Diethylhydroxylamine

By formula: C4H10NO- + H+ = C4H11NO

Quantity Value Units Method Reference Comment
Deltar1551. ± 8.8kJ/molG+TSBartmess, Basso, et al., 1983gas phase; See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values
Quantity Value Units Method Reference Comment
Deltar1523. ± 8.4kJ/molIMREBartmess, Basso, et al., 1983gas phase; See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bartmess, Basso, et al., 1983
Bartmess, J.E.; Basso, T.; eorgiadis, R.M., The electron affinity of a nitroxide radical, J. Phys. Chem., 1983, 87, 912. [all data]

Mahoney, Mendenhall, et al., 1973
Mahoney, L.R.; Mendenhall, G.D.; Ingold, K.U., Calorimetric and Equilibrium Studies on Some Stable Nitroxide and Iminoxy Radicals. Approximate O-H BDEs in Hydroxylamines and Oximes., J. Am. Chem. Soc., 1973, 95, 26, 8610, https://doi.org/10.1021/ja00807a018 . [all data]

Bordwell and Liu, 1996
Bordwell, F.G.; Liu, W.-Z., Solvent Effects on Homolytic Bond Dissociation Energies of Hydroxylic Acids, J. Am. Chem. Soc., 1996, 118, 44, 10819-10823, https://doi.org/10.1021/ja961469q . [all data]


Notes

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