7-Me-cycloheptatrienide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C8H9- + Hydrogen cation = 7-Methylcycloheptatriene

By formula: C8H9- + H+ = C8H10

Quantity Value Units Method Reference Comment
Δr371.0 ± 2.5kcal/molG+TSMishima, Kinoshita, et al., 2002gas phase; Reprotonation likely to be on C-1, giving 1-alkyl-cycloheptatriene - JEB
Quantity Value Units Method Reference Comment
Δr363.3 ± 2.0kcal/molIMREMishima, Kinoshita, et al., 2002gas phase; Reprotonation likely to be on C-1, giving 1-alkyl-cycloheptatriene - JEB

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mishima, Kinoshita, et al., 2002
Mishima, M.; Kinoshita, T.; Hattori, Y.; Takeuchi, K., Gas-phase acidities of cycloheptatrienes: effects of alkyl groups on the stability of carbanions, Eur. J. Mass Spectrom., 2002, 8, 1, 359-366, https://doi.org/10.1255/ejms.499 . [all data]


Notes

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