PBr4 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-99.6 ± 2.5kcal/molTherHeil, Check, et al., 2002 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Bromine anion + Phosphorus tribromide = Br4P-

By formula: Br- + Br3P = Br4P-

Quantity Value Units Method Reference Comment
Δr15.5 ± 1.4kcal/molCIDTHeil, Check, et al., 2002gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Heil, Check, et al., 2002
Heil, T.E.; Check, C.E.; Lobring, K.C.; Sunderlin, L.S., The thermochemistry of phosphorus tetrahalide anions, J. Phys. Chem. A, 2002, 106, 42, 10043-10048, https://doi.org/10.1021/jp021386y . [all data]


Notes

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