CF3H..pMe-C6H4CðC anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-112.6 ± 2.8kcal/molTherChabinyc and Brauman, 2000Original dG=8.3 at 350K; dS based on symmetry alone

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C9H7- + Fluoroform = C10H8F3-

By formula: C9H7- + CHF3 = C10H8F3-

Quantity Value Units Method Reference Comment
Δr18.8 ± 1.0kcal/molIMREChabinyc and Brauman, 2000gas phase; Original dG=8.3 at 350K; dS based on symmetry alone
Quantity Value Units Method Reference Comment
Δr9.9 ± 1.0kcal/molIMREChabinyc and Brauman, 2000gas phase; Original dG=8.3 at 350K; dS based on symmetry alone

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chabinyc and Brauman, 2000
Chabinyc, M.L.; Brauman, J.I., Unusual ionic hydrogen bonds: Complexes of acetylides and fluoroform, J. Am. Chem. Soc., 2000, 122, 36, 8739-8745, https://doi.org/10.1021/ja000806z . [all data]


Notes

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