Tb2Cl7 anion
- Formula: Cl7Tb2-
- Molecular weight: 566.022
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: TbCl4- + Cl3Tb = Cl7Tb2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 242. ± 38. | kJ/mol | TDEq | Kudin, Vorob'ev, et al., 2007 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
ΔrH° | 374. ± 10. | kJ/mol | TDEq | Khasanshin, Kudin, et al., 1999 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: TbCl4- + Cl3Tb = Cl7Tb2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 242. ± 38. | kJ/mol | TDEq | Kudin, Vorob'ev, et al., 2007 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
ΔrH° | 374. ± 10. | kJ/mol | TDEq | Khasanshin, Kudin, et al., 1999 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E.,
The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions,
Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X
. [all data]
Khasanshin, Kudin, et al., 1999
Khasanshin, I.V.; Kudin, L.S.; Pogrebnoi, A.M.,
A mass spectrometric study of saturated vapor over terbium trichloride and the TbCl3-DyCl3 system,
Russ. J. Phys. Chem., 1999, 73, 849-855. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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