CF3CF2CH2O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H2F5O- + Hydrogen cation = 2,2,3,3,3-Pentafluoro-1-propanol

By formula: C3H2F5O- + H+ = C3H3F5O

Quantity Value Units Method Reference Comment
Δr1487. ± 26.kJ/molG+TSDawson and Jennings, 1977gas phase; Between (CF3)2CHOH, CF3CH2OH; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr1459. ± 25.kJ/molIMRBDawson and Jennings, 1977gas phase; Between (CF3)2CHOH, CF3CH2OH; value altered from reference due to change in acidity scale

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.83 ± 0.28D-EADawson and Jennings, 1977Between (CF3)2CHOH, CF3CH2OH; value altered from reference due to change in acidity scale

Protonation reactions

C3H2F5O- + Hydrogen cation = 2,2,3,3,3-Pentafluoro-1-propanol

By formula: C3H2F5O- + H+ = C3H3F5O

Quantity Value Units Method Reference Comment
Δr1487. ± 26.kJ/molG+TSDawson and Jennings, 1977gas phase; Between (CF3)2CHOH, CF3CH2OH; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr1459. ± 25.kJ/molIMRBDawson and Jennings, 1977gas phase; Between (CF3)2CHOH, CF3CH2OH; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dawson and Jennings, 1977
Dawson, J.H.J.; Jennings, K.R., Relative gas phase acidities of some fluoroalcohols, Int. J. Mass Spectrom. Ion Phys., 1977, 25, 47. [all data]


Notes

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