2,5-diCF3-phenide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C8H3F6- + Hydrogen cation = Benzene, 1,4-bis(trifluoromethyl)-

By formula: C8H3F6- + H+ = C8H4F6

Quantity Value Units Method Reference Comment
Δr1570. ± 13.kJ/molG+TSSchlosser, Mongin, et al., 1998gas phase
Quantity Value Units Method Reference Comment
Δr1534. ± 13.kJ/molIMRESchlosser, Mongin, et al., 1998gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C8H3F6- + Hydrogen cation = Benzene, 1,4-bis(trifluoromethyl)-

By formula: C8H3F6- + H+ = C8H4F6

Quantity Value Units Method Reference Comment
Δr1570. ± 13.kJ/molG+TSSchlosser, Mongin, et al., 1998gas phase
Quantity Value Units Method Reference Comment
Δr1534. ± 13.kJ/molIMRESchlosser, Mongin, et al., 1998gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schlosser, Mongin, et al., 1998
Schlosser, M.; Mongin, F.; Porwisiak, J.; Dmowski, W.; Buker, H.H.; Nibbering, N.M.M., Bis- and Oligo(trifluoromethyl)benzenes: Hydrogen/Metal Exchange Rates and Gas-Phase Acidities., Chem. Eur. J., 1998, 4, 7, 1281, https://doi.org/10.1002/(SICI)1521-3765(19980710)4:7<1281::AID-CHEM1281>3.0.CO;2-I . [all data]


Notes

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