MeOCF3..Cl anion
- Formula: C2H3ClF3O-
- Molecular weight: 135.493
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
+ C3H3F3O- = C2H3ClF3O-
By formula: Cl- + C3H3F3O- = C2H3ClF3O-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.60 ± 0.40 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 7.7 ± 1.0 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase |
C2H3ClF3O- + 2C3H3F3O- = C4H6ClF6O2-
By formula: C2H3ClF3O- + 2C3H3F3O- = C4H6ClF6O2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.70 ± 0.40 | kcal/mol | N/A | Bogdanov, Lee, et al., 2001 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 5.6 ± 1.0 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bogdanov, Lee, et al., 2001
Bogdanov, B.; Lee, H.J.S.; McMahon, T.B.,
Influence of fluorine substitution on the structures and thermochemistry of chloride ion-ether complexes in the gas phase,
Int. J. Mass Spectrom., 2001, 210, 387-402, https://doi.org/10.1016/S1387-3806(01)00404-3
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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