MeOO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH3O2- + Hydrogen cation = Methyl peroxide

By formula: CH3O2- + H+ = CH4O2

Quantity Value Units Method Reference Comment
Δr374.63 ± 0.76kcal/molG+TSBlanksby, Ramond, et al., 2001gas phase
Quantity Value Units Method Reference Comment
Δr367.60 ± 0.70kcal/molIMREBlanksby, Ramond, et al., 2001gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.1610 ± 0.0050LPESBlanksby, Ramond, et al., 2001 

Protonation reactions

CH3O2- + Hydrogen cation = Methyl peroxide

By formula: CH3O2- + H+ = CH4O2

Quantity Value Units Method Reference Comment
Δr374.63 ± 0.76kcal/molG+TSBlanksby, Ramond, et al., 2001gas phase
Quantity Value Units Method Reference Comment
Δr367.60 ± 0.70kcal/molIMREBlanksby, Ramond, et al., 2001gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blanksby, Ramond, et al., 2001
Blanksby, S.J.; Ramond, T.M.; Davico, G.E.; Nimlos, M.R.; Kato, S.; Bierbaum, V.M.; Lineberger, W.C.; Ellison, Negative-ion photoelectron spectroscopy, gas-phase acidity, and thermochemistry of the peroxyl radicals CH3OO and CH3CH2OO, J. Am. Chem. Soc., 2001, 123, 39, 9585-9596, https://doi.org/10.1021/ja010942j . [all data]


Notes

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