DO anion
- Formula: DO-
- Molecular weight: 18.0141
- Information on this page:
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Clustering reactions
DO- + = (DO- •
)
By formula: DO- + D2O = (DO- • D2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 26.80 ± 0.70 | kcal/mol | TDAs | Meot-ner and Sieck, 1986 | gas phase |
| ΔrH° | 22.5 ± 2.0 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 20.1 ± 1.1 | kcal/mol | TDAs | Meot-ner and Sieck, 1986 | gas phase |
| ΔrG° | 16.9 ± 2.0 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
(DO- • ) +
= (DO- • 2
)
By formula: (DO- • D2O) + D2O = (DO- • 2D2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.4 ± 1.0 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 10.70 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
(DO- • 2) +
= (DO- • 3
)
By formula: (DO- • 2D2O) + D2O = (DO- • 3D2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 15.1 ± 1.0 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 7.70 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
(DO- • 3) +
= (DO- • 4
)
By formula: (DO- • 3D2O) + D2O = (DO- • 4D2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.2 ± 1.0 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 5.50 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
(DO- • 4) +
= (DO- • 5
)
By formula: (DO- • 4D2O) + D2O = (DO- • 5D2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.1 ± 1.0 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 4.20 | kcal/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Meot-ner and Sieck, 1986
Meot-ner, M.; Sieck, L.W.,
Relative acidities of water and methanol, and the stabilities of the dimer adducts,
J. Phys. Chem., 1986, 90, 6687. [all data]
Arshadi and Kebarle, 1970
Arshadi, M.; Kebarle, P.,
Hydration of OH- and O2- in the Gas Phase. Comparative Solvation of OH- by Water and the Hydrogen Halides. Effect of Acidity,
J. Phys. Chem., 1970, 74, 7, 1483, https://doi.org/10.1021/j100702a015
. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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