(MeCl)5..Cl anion
- Formula: C5H15Cl6-
- Molecular weight: 287.891
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -195.88 | kcal/mol | Ther | Hiraoka, Mizuno, et al., 2001 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C4H12Cl5- + 5 = C5H15Cl6-
By formula: C4H12Cl5- + 5CH3Cl = C5H15Cl6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.20 | kcal/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 0.83 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase |
C5H15Cl6- + 6 = C6H18Cl7-
By formula: C5H15Cl6- + 6CH3Cl = C6H18Cl7-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.80 | kcal/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 0.43 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka, Mizuno, et al., 2001
Hiraoka, K.; Mizuno, T.; Iino, T.; Eguchi, D.; Yamabe, S.,
Characteristic changes of bond energies for gas-phase cluster ions of halide ions with methane and chloromethanes,
J. Phys. Chem. A, 2001, 105, 20, 4887-4893, https://doi.org/10.1021/jp010143n
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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