(MeCl)4..Cl anion
- Formula: C4H12Cl5-
- Molecular weight: 237.404
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C3H9Cl4- + 4 = C4H12Cl5-
By formula: C3H9Cl4- + 4CH3Cl = C4H12Cl5-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 31.8 | kJ/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 5.61 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase |
C4H12Cl5- + 5 = C5H15Cl6-
By formula: C4H12Cl5- + 5CH3Cl = C5H15Cl6-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.9 | kJ/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 3.5 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka, Mizuno, et al., 2001
Hiraoka, K.; Mizuno, T.; Iino, T.; Eguchi, D.; Yamabe, S.,
Characteristic changes of bond energies for gas-phase cluster ions of halide ions with methane and chloromethanes,
J. Phys. Chem. A, 2001, 105, 20, 4887-4893, https://doi.org/10.1021/jp010143n
. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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