mCF3-C6H5SiMe2 anion
- Formula: C9H10F3Si-
- Molecular weight: 203.2570
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
C9H10F3Si- + = C9H11F3Si
By formula: C9H10F3Si- + H+ = C9H11F3Si
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1574. ± 9.2 | kJ/mol | G+TS | Irie, Kikukawa, et al., 2001 | gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1541. ± 8.4 | kJ/mol | IMRE | Irie, Kikukawa, et al., 2001 | gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Irie, Kikukawa, et al., 2001
Irie, M.; Kikukawa, K.; Shimizu, N.; Mishima, M.,
Gas-phase acidities of aryldimethylsilanes,
J. Chem. Soc. Perkin Trans., 2001, 2, 6, 923-928, https://doi.org/10.1039/b100488n
. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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