mCH2Cl-C6H4CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C8H8Cl- + Hydrogen cation = Benzene, 1-(chloromethyl)-4-methyl-

By formula: C8H8Cl- + H+ = C8H9Cl

Quantity Value Units Method Reference Comment
Δr375.1 ± 2.3kcal/molD-EAHammad and Wenthold, 2000gas phase
Quantity Value Units Method Reference Comment
Δr367.9 ± 2.4kcal/molH-TSHammad and Wenthold, 2000gas phase

Chlorine anion = C8H8Cl-

By formula: Cl- = C8H8Cl-

Quantity Value Units Method Reference Comment
Δr20.1 ± 1.6kcal/molCIDTHammad and Wenthold, 2000gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.194 ± 0.053CIDCHammad and Wenthold, 2000 

Protonation reactions

C8H8Cl- + Hydrogen cation = Benzene, 1-(chloromethyl)-4-methyl-

By formula: C8H8Cl- + H+ = C8H9Cl

Quantity Value Units Method Reference Comment
Δr375.1 ± 2.3kcal/molD-EAHammad and Wenthold, 2000gas phase
Quantity Value Units Method Reference Comment
Δr367.9 ± 2.4kcal/molH-TSHammad and Wenthold, 2000gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion = C8H8Cl-

By formula: Cl- = C8H8Cl-

Quantity Value Units Method Reference Comment
Δr20.1 ± 1.6kcal/molCIDTHammad and Wenthold, 2000gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hammad and Wenthold, 2000
Hammad, L.A.; Wenthold, P.G., Synthesis, characterization, and reactivity of the m-xylylene anion in the gas phase. The enthalpy of formation of m-xylylene, J. Am. Chem. Soc., 2000, 122, 45, 11203-11211, https://doi.org/10.1021/ja002138n . [all data]


Notes

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