mCH2Cl-C6H4CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C8H8Cl- + Hydrogen cation = Benzene, 1-(chloromethyl)-4-methyl-

By formula: C8H8Cl- + H+ = C8H9Cl

Quantity Value Units Method Reference Comment
Δr1569. ± 9.6kJ/molD-EAHammad and Wenthold, 2000gas phase
Quantity Value Units Method Reference Comment
Δr1539. ± 10.kJ/molH-TSHammad and Wenthold, 2000gas phase

Chlorine anion = C8H8Cl-

By formula: Cl- = C8H8Cl-

Quantity Value Units Method Reference Comment
Δr84.1 ± 6.7kJ/molCIDTHammad and Wenthold, 2000gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hammad and Wenthold, 2000
Hammad, L.A.; Wenthold, P.G., Synthesis, characterization, and reactivity of the m-xylylene anion in the gas phase. The enthalpy of formation of m-xylylene, J. Am. Chem. Soc., 2000, 122, 45, 11203-11211, https://doi.org/10.1021/ja002138n . [all data]


Notes

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